Dirhodium(II)/Phosphine Catalyst with Chiral Environment at Bridging Site and Its Application in Enantioselective Atropisomer Synthesis
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DOI: 10.1021/acscentsci.2c01207
Abstract: A dirhodium(II)/phosphine catalyst with a chiral environment at the bridging site was developed for the asymmetric arylation of phenanthrene-9,10-diones with arylboronic acids. In contrast to the classic chiral bridging carboxylic acid (or derivatives) ligand strategy… read more here.
Keywords: phosphine; phosphine catalyst; dirhodium; dirhodium phosphine ... See more keywords