Bis(α-hydroxycycloalkyl)phosphine Oxides Obtained from White Phosphorus via Phosphine Oxide H3 PO: Synthesis, Molecular Structure, Coordination Properties and Biological Activity.
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DOI: 10.1002/cplu.202000220
Abstract: Reaction of the electrochemically in situ from elemental white phosphorus generated phosphine oxide H3 PO in a single electrochemical cell, supplied with lead cathode and aluminium anode, with cyclic ketones (cyclopentanone and cyclohexanone) results in formation… read more here.
Keywords: phosphine oxide; white phosphorus; phosphine; bis ... See more keywords
Phosphine oxide-Sc(OTf)3 catalyzed enantioselective bromoaminocyclization of tri-substituted allyl N-tosylcarbamates
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DOI: 10.1007/s11426-017-9192-x
Abstract: Phosphine oxide-Sc(OTf)3 catalyzed regio- and enantioselective bromoaminocyclization of tri-substituted allyl N-tosylcarbamates is described. A wide variety of optically active tertiary 5-bromo-1,3-oxazinan-2-ones can be obtained with high regio-and enantioselectivity. read more here.
Keywords: phosphine oxide; otf catalyzed; tri substituted; bromoaminocyclization tri ... See more keywords
Lanthanide phosphine oxide complexes
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DOI: 10.1016/j.ccr.2016.09.012
Abstract: Abstract Phosphine oxide complexes of lanthanide metal have been studied to elucidate the fundamental aspects of their structural chemistry and to develop important technological applications mainly in the reprocessing of nuclear fuels and in photoluminescent… read more here.
Keywords: oxide complexes; phosphine oxide; chemistry; complexes lanthanide ... See more keywords
Achieving host-free near-ultraviolet electroluminescence via electronic state engineering with phosphine oxide
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DOI: 10.1016/j.cej.2021.132327
Abstract: Abstract Developing near-ultraviolet (NUV) emitters with board band gap and high photoluminescence quantum efficiency (PLQY) is a formidable challenge for organic light-emitting diode (OLED) applications. Herein, two NUV emitters PhImPOCz and PhImPOtBuCz were designed on… read more here.
Keywords: state; engineering; phosphine oxide; electronic state ... See more keywords
Facile high yield, excellent catalytic performance of polyoxometalate-based lanthanide phosphine oxide complexes: Syntheses, structures, photocatalysis and THz spectra.
Sign Up to like & getrecommendations! Published in 2021 at "Environmental research"
DOI: 10.1016/j.envres.2021.112267
Abstract: Water pollution, which continuously threatens human health and the sustainable development of society, has become a major concern. Photocatalytic degradation is an effective strategy to remove organic dyes from wastewater. For this strategy, it is… read more here.
Keywords: oxide complexes; phosphine oxide; high yield; photocatalysis ... See more keywords
Thermal decomposition of polyimides containing phosphine-oxide units
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DOI: 10.1016/j.jaap.2018.06.015
Abstract: Abstract This work details analyses of the thermal decomposition behaviour of three phosphine-oxide containing aromatic processable polyimides. The polymers exhibited high thermal stability with initial decomposition temperatures in the range of 473–483 °C and a char… read more here.
Keywords: phosphine oxide; decomposition; polyimides containing; containing phosphine ... See more keywords
Synthesis, characterization, and crystal structure of mercury(II) complex containing new phosphine oxide salt
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DOI: 10.1016/j.molstruc.2016.09.079
Abstract: Abstract The reaction of new phosphonium-phosphine oxide salt [P(O)Ph2(CH2)2PPh2CH2C(O)C6H4NO2]Br (1) with mercury(II) iodide in a methanolic solution yielded [P(O)Ph2(CH2)2PPh2CH2C(O)C6H4NO2]2[Hg2I5Br](2). These two compounds were fully characterized by elemental analysis, IR, 1H, 31P, and 13C NMR spectra.… read more here.
Keywords: phosphine oxide; structure; crystal; oxide salt ... See more keywords
Structure-property relationship of phosphine oxide based thermally activated delayed fluorescence molecules: First-principles study
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DOI: 10.1016/j.orgel.2018.04.032
Abstract: Abstract Three phosphine oxide (P O) based blue TADF emitters with weak acceptors and strong donors (WASD) were reported recently by Xu’ group [Chem. Mater. 2016, 28, 5667], which provides a new way for the… read more here.
Keywords: phosphine oxide; oxide based; first principles; relationship ... See more keywords
Diphenylmorpholine CMPO: Synthesis, coordination behavior and extraction studies of actinides
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DOI: 10.1016/j.poly.2017.11.036
Abstract: Abstract Carbamoylmethyl phosphine oxide (CMPO) derivatives are well known ligands in the separation and extraction of trivalent lanthanides and actinides from nuclear waste. The substituents of CMPO play major role in their selectivity and extractability.… read more here.
Keywords: phosphine oxide; extraction; cmpo; diphenylmorpholine cmpo ... See more keywords
Evaluation of bifunctional chiral phosphine oxide catalysts for the asymmetric hydrosilylation of ketimines
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DOI: 10.1016/j.tet.2019.130733
Abstract: Abstract A series of bifunctional phosphine oxides have been prepared and evaluated as catalysts for the trichlorosilane mediated asymmetric hydrosilylation of ketimines. bis-Phosphine oxides, hydroxy-phosphine oxides, and biaryl phosphine oxides all demonstrated good catalytic activity,… read more here.
Keywords: hydrosilylation ketimines; phosphine oxide; phosphine; phosphine oxides ... See more keywords
Recent advances in asymmetric phosphine oxide catalysis
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DOI: 10.1016/j.tetlet.2019.151421
Abstract: Abstract Phosphine oxides are versatile catalysts in organic synthesis and mediate a broad range of transformations. In this digest, we reviewed the recent developments in phosphine oxide-catalyzed asymmetric reactions. The enantioselective double aldol reactions, enantioselective… read more here.
Keywords: phosphine oxide; asymmetric phosphine; advances asymmetric; recent advances ... See more keywords