Phosphine-Stabilized Germasilenylidene: Source for a Silicon-Atom Transfer.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c01361
Abstract: A phosphine-stabilized germasilenylidene is synthesized following the pathway of SiCl4 oxidative addition at a germylene-phosphine Lewis pair. Low-temperature reduction using {(MesNacnac)Mg}2 resulted in a chlorosilylene intermediate and finally a molecule exhibiting a Ge═Si: motif. Inside… read more here.
Keywords: stabilized germasilenylidene; silicon atom; phosphine stabilized;
Phosphine-Stabilized Hidden Ground States in Gold Clusters Investigated via a Aun(PH3)m Database
Sign Up to like & getrecommendations! Published in 2022 at "ACS Nano"
DOI: 10.1021/acsnano.2c07223
Abstract: Nanoclusters are promising materials for catalysis and sensing due to their large surface areas and unique electronic structures which can be tailored through composition, geometry, and chemistry. However, relationships correlating synthesis parameters directly to outcomes… read more here.
Keywords: phosphine; hidden ground; database; aun ph3 ... See more keywords