Tertiary phosphine‐supported diiron model complexes relevant to [FeFe]‐hydrogenases
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DOI: 10.1002/aoc.7608
Abstract: In an effort to better probe the structure–function relationship on the biological [Fe4S4] cluster of [FeFe]‐hydrogenases, a new library of tertiary phosphine‐supported diiron dithiolate complexes [Fe2(μ‐adtNR)(CO)5{P(C6H4X)3}] (1–3) with various substituents (X = F vs. H vs. Me),… read more here.
Keywords: phosphine supported; tertiary phosphine; fefe hydrogenases; diiron model ... See more keywords