Non-Metal-Catalyzed Heterodehydrocoupling of Phosphines and Hydrosilanes: Mechanistic Studies of B(C6F5)3-Mediated Formation of P-Si Bonds.
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DOI: 10.1021/jacs.7b09175
Abstract: Non-metal-catalyzed heterodehydrocoupling of primary and secondary phosphines (R1R2PH, R2 = H or R1) with hydrosilanes (R3R4R5SiH, R4, R5 = H or R3) to produce synthetically useful silylphosphines (R1R2P-SiR3R4R5) has been achieved using B(C6F5)3 as the… read more here.
Keywords: catalyzed heterodehydrocoupling; mechanistic studies; metal catalyzed; phosphines hydrosilanes ... See more keywords