Insights into the Coordination Behavior of Methyl-Substituted Phosphinic Acids with Actinides.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01287
Abstract: The electronic structure and complexation behavior of methyl-substituted phosphinic acids with U(VI) and Pu(IV) were explored by applying quantum chemical methods. In contrast to Ingold's classification, our results indicate that the methyl group is electron-withdrawing,… read more here.
Keywords: substituted phosphinic; complexation; behavior methyl; methyl substituted ... See more keywords
Unprecedented Convergent Synthesis of Sugar-Functionalization of Phosphinic Acids under Metal-Free Conditions
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c00712
Abstract: A novel TEA-catalyzed sugar-esterification of phosphinic acids was used as a general and efficient approach for the synthesis of a variety of phosphinates without any transition metal. The high efficiency of the current methodology and… read more here.
Keywords: unprecedented convergent; synthesis; convergent synthesis; phosphinic acids ... See more keywords