Synthesis of Phosphinic Amides from Chlorophosphines and Hydroxyl Amines via P(III) to P(V) Rearrangement.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c00229
Abstract: Phosphoranyl radicals are essential mediators to bring about new radicals but often produce a stoichiometric amount of phosphine oxide/sulfide waste. Herein, we devised a phosphorus-containing species as a radical precursor, but without the generation of… read more here.
Keywords: iii rearrangement; via iii; amides chlorophosphines; synthesis phosphinic ... See more keywords
Tailored trisubstituted chiral Cp x RhIII catalysts for kinetic resolutions of phosphinic amides.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical science"
DOI: 10.1039/c7sc05411d
Abstract: A trisubstituted chiral Cp x ligand family is introduced. Based on the disubstituted atropchiral Cp x ligand scaffold, the introduction of a bulky third substituent at the central position of the Cp ring leads to… read more here.
Keywords: tailored trisubstituted; kinetic resolutions; resolutions phosphinic; trisubstituted chiral ... See more keywords