Structural, Spectroscopic, and Computational Analysis of Heterometallic Thorium Phosphinidiide Complexes.
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DOI: 10.1021/acs.inorgchem.1c02308
Abstract: To synthesize complexes with thorium-phosphorus multiple-bond character, reactions of (C5Me5)2Th[P(H)Mes]2 with monovalent alkali-metal bases, MN(SiMe3)2, as well as CuMes, have been investigated. The results with MN(SiMe3)2 are phosphinidiide complexes of the form {(C5Me5)2Th[μ2-P(Mes)][μ2-P(H)Mes]M(L)n}2 (M =… read more here.
Keywords: c5me5 2th; phosphinidiide complexes; thorium; structural spectroscopic ... See more keywords