A ruthenium(ii) bis(phosphinophosphinine) complex as a precatalyst for transfer-hydrogenation and hydrogen-borrowing reactions.
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DOI: 10.1039/c7dt01022b
Abstract: The 2-phosphinophosphinine 2-PPh2-3-Me-6-SiMe3-PC5H2 (2) has been prepared and was shown to act as a κ2-chelating ligand in cis-[RuCl2(2)2] (4). Complex 4 was a competent precatalyst for the room temperature transfer hydrogenation of acetophenone (0.1 mol%… read more here.
Keywords: precatalyst; ruthenium bis; transfer hydrogenation; phosphinophosphinine ... See more keywords