Facile Access to Phospholene Fused Polycycles through Intramolecular Alder‐ene Reaction of Phosphole Sulfides
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DOI: 10.1002/ejoc.202401294
Abstract: We have developed a simple, metal‐free annulation of phosphole sulfides through intramolecular Alder‐ene reaction involving a 1,6‐enyne component. This atom‐efficient cyclization pathway provides phospholene fused polycycles with high yields and excellent regioselectivity. The 1,6‐enyne cyclization… read more here.
Keywords: phospholene fused; phosphole; ene reaction; intramolecular alder ... See more keywords
Facile modification of phosphole-based aggregation-induced emission luminogens with sulfonyl isocyanates
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc00308f
Abstract: Phosphole oxides undergo a highly chemoselective reaction with sulfonyl isocyanates forming sulfonylimino phospholes in high yields. This facile modification proved to be a powerful tool for obtaining new phosphole-based aggregation-induced emission (AIE) luminogens with high… read more here.
Keywords: sulfonyl isocyanates; phosphole; aggregation induced; facile modification ... See more keywords