Dynamic kinetic resolution of 1-substituted-3-methyl-3-phospholene oxides via the formation of diastereomeric alkoxyphospholenium salts
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DOI: 10.1016/j.tet.2018.07.058
Abstract: Abstract A dynamic kinetic resolution method based on the formation of covalent diastereomeric intermediates was elaborated for the preparation of enantiomerically enriched 1-substituted-3-methyl-3-phospholene oxides. The 3-phospholene oxides were first converted to the corresponding chloro-3-phospholenium chlorides.… read more here.
Keywords: phospholene oxides; resolution; kinetic resolution; dynamic kinetic ... See more keywords