Reductive Ring Opening of a Cyclo-Tri(phosphonio)methanide Dication to a Phosphanylcarbodiphosphorane: In Situ UV-Vis Spectroelectrochemistry and Gold Coordination
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DOI: 10.1021/acs.organomet.7b00597
Abstract: The formal two-electron reduction of the cyclo-tri(phosphonio)methanide dication 12+ results in a ring-opening reaction via C–P bond cleavage to yield the unique phosphanyl-functionalized carbodiphosphorane 2. In situ spectroelectrochemical investigations of the reduction of dication 12+… read more here.
Keywords: ring opening; dication; phosphonio methanide; tri phosphonio ... See more keywords