Base-Stabilized Cationic Silyne with a π-Accepting Phosphonio Substituent.
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DOI: 10.1021/acs.inorgchem.3c00513
Abstract: A base-stabilized C-phosphonio-Si-amino-silyne 3 was synthesized, using an original method, through a coupling reaction between two Lewis-base-stabilized low-valent species: a silyliumylidene ion 1 and a P,S-bis-ylide 2 [C(0)-complex]. This new isolable cationic silyne 3 displays… read more here.
Keywords: base stabilized; phosphonio substituent; silyne; stabilized cationic ... See more keywords