Phosphorescent Cyclometalated Palladium(II) and Platinum(II) Complexes Derived from Diaminocarbene Precursors
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.3c03346
Abstract: Metal-mediated self-assembly of isocyanides and methyl 4-aminopyrimidine-5-carboxylate leads to luminescent PdII and PtII complexes featuring C,N-cyclometalated acyclic diaminocarbene (ADC) ligands. The solid-state luminescent properties of these diaminocarbene derivatives are attributed to their triplet-state metal/metal-to-ligand charge-transfer… read more here.
Keywords: phosphorescent cyclometalated; complexes derived; palladium platinum; platinum complexes ... See more keywords
Phosphorescent cyclometalated platinum(II) complexes with phenyldiazine N^C ligands.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03690h
Abstract: A series of phosphorescent platinum(II) complexes containing various phenyldiazine-type bidentate N^C ligands have been successfully synthesized and characterized. Structural modifications have been made to bidentate cyclometalating ligands regarding the nature of the diazine ring (pyrimidine,… read more here.
Keywords: platinum complexes; solid state; phosphorescent cyclometalated; ligand ... See more keywords