Copper and Photocatalytic Radical Relay Enabling Fluoroalkylphosphorothiolation of Alkenes: Modular Synthesis of Fluorine-Containing S-Alkyl Phosphorothioates and Phosphorodithioates.
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DOI: 10.1021/acs.orglett.1c03608
Abstract: A photoredox and copper-catalyzed fluoroalkylphosphorothiolation of activated and unactivated alkenes via a radical relay mechanism is reported. By employing fluoroalkyl halides as radical precursors and P(O)SH or P(S)SH compounds as coupling partners, a wide range… read more here.
Keywords: copper photocatalytic; phosphorothioates phosphorodithioates; fluoroalkylphosphorothiolation; alkyl phosphorothioates ... See more keywords