Cesium carbonate-catalyzed synthesis of phosphorothioates via S-phosphination of thioketones.
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DOI: 10.1039/d2cc04331a
Abstract: A highly efficient and environmentally-friendly base-mediated transition metal-free direct thiophilic catalytic approach is reported for the synthesis of S-benzhydryl-phosphorothioates by reacting phosphite nucleophiles with diarylmethanethione. A wide variety of thioketones were coupled with different phosphite… read more here.
Keywords: via phosphination; synthesis phosphorothioates; phosphorothioates via; carbonate catalyzed ... See more keywords