Synthesis of iron(III)-carbonyl complex with variable wavelength range for CO release depending on protonation and deprotonation of axial phosphorous ligands
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DOI: 10.1016/j.jorganchem.2021.121843
Abstract: Abstract N,C,S-pincer iron(III) carbonyl complexes with two phosphorus ligands—trans-[Fe(L-κ3N,C,S)(CO)(PR3)2]PF6 ([1]PF6, R = Me; [ 2 ]PF6, R = OEt) are light-inducible CO releasers under ambient conditions. Optical wavelength ranges corresponding to such a CO release depend on the phosphorous… read more here.
Keywords: phosphorous ligands; pf6; iron iii; iii carbonyl ... See more keywords