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Published in 2019 at "Nature Communications"
DOI: 10.1038/s41467-018-07957-6
Abstract: The formation of non-covalent directional interactions, such as hydrogen or halogen bonds, is a central concept of materials design, which hinges on using small compact atoms of the 2nd period, notably nitrogen and oxygen, as…
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Keywords:
halogen bonded;
arsenic antimony;
phosphorus arsenic;
halogen ... See more keywords
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Published in 2018 at "Chemical communications"
DOI: 10.1039/c7cc09730a
Abstract: Different reaction pathways were determined between thermolysis and photolysis reactions of the butterfly complex [{CpBIGFe(CO)2}2(μ,η1:1-As4)] (1b). The thermolysis leads to novel arsenic-rich compounds [(CpBIGFe)2(μ,η4:4-As4)] (2b), [(CpBIGFe)3(μ3,η4:4:4-As6)] (4) and [CpBIGFe(η5-As5)] (5), whereas the photolysis of [{CpBIGFe(CO)2}2(μ,η1:1-E4)]…
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Keywords:
reactivity phosphorus;
differences reactivity;
phosphorus arsenic;
cpbigfe as4 ... See more keywords