Stereoselective Transesterification of P‐Chirogenic Hydroxybinaphthyl Phosphinates
Sign Up to like & getrecommendations! Published in 2022 at "ChemistryOpen"
DOI: 10.1002/open.202100294
Abstract: Abstract The substitution reaction of phosphinates with a binaphthyloxy group at the phosphorus atom with lithium alkoxides proceeded with good to high efficiencies to give P‐chirogenic phosphinates with a high enantiomeric ratio. As alcohols, primary,… read more here.
Keywords: chirogenic hydroxybinaphthyl; reaction; substitution reaction; transesterification chirogenic ... See more keywords
cAMPS derivatives. A minireview over synthetic medicinal chemistry.
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DOI: 10.1016/j.bioorg.2019.103152
Abstract: Cyclic nucleosides belonging to the cAMPS system can exert antagonistic or agonistic effects on the cAMP/PKA type 1 inhibitory pathway affecting T-lymphocyte replications. The stereochemistry at the phosphorus atom in the phosphate group is important… read more here.
Keywords: minireview synthetic; derivatives minireview; camps derivatives; chemistry ... See more keywords