Pentavalent P…π phosphorus bonding with associated Cl…π halogen bonding in influencing the geometry of POCl3-Phenylacetylene heterodimers: Evidence from matrix isolation infrared spectroscopy and ab initio computations
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DOI: 10.1016/j.molstruc.2020.129288
Abstract: Abstract Of the two diverse oxidation states, phosphorus exists in its pentavalent state in a majority of real-life systems. In the present study, the role of Cl…π halogen bonding with co-operative pentavalent P…π phosphorus bonding in… read more here.
Keywords: phosphorus bonding; spectroscopy; halogen bonding; geometry ... See more keywords