LAUSR

Phosphorus-Involved Wagner-Meerwein Rearrangement of Phosphiranes: An Entry to Four-Membered Phosphacycles.

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1 Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c04052

Abstract: Phosphenium ions [R2P]+ are important and highly reactive dicoordinate phosphorus species. Herein, we report a rearrangement of the carbocation into the phosphenium cation driven by ring strain. This phosphorus-involved Wagner-Meerwein rearrangement pathway converted the 1-acylphosphirane… read more here.

Keywords: phosphorus involved; wagner meerwein; involved wagner; meerwein rearrangement ... See more keywords