Insertion of a Nontrigonal Phosphorus Ligand into a Transition Metal-Hydride: Direct Access to a Metallohydrophosphorane.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b05156
Abstract: The synthesis and reactivity of an NPN-chelating ligand containing a nontrigonal phosphorous triamide center (L1 = P(N( o-N(2-pyridyl)C6H4)2) is reported. Metalation of L1 with RuCl2(PPh3)3 gives RuCl2(PPh3)(L1) (2). By contrast, metalation of L1 with RuHCl(CO)(PPh3)3… read more here.
Keywords: pph3; nontrigonal phosphorus; phosphorus ligand; insertion nontrigonal ... See more keywords
Isolation of heterometallic cerium(iii) complexes with a multidentate nitrogen-phosphorus ligand.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt04555d
Abstract: Heterometallic complexes play an important role in catalysis and activation of small molecules due to the synergistic effects from different metals. Here we report a straightforward strategy to construct a series of heterobimetallic complexes of… read more here.
Keywords: phosphorus ligand; nitrogen phosphorus; multidentate nitrogen; cerium iii ... See more keywords