Synthesis of 5-phosphoryl-substituted 1,3,4(3H)-thiadiazolones
Sign Up to like & getrecommendations! Published in 2019 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-019-2673-2
Abstract: Reactions of various phosphorylthioformic acid morpholides with hydrazine afford phosphorylthioformhydrazides. The latter react under mild conditions with N, N′-carbonyldiimidazole to form novel 5-phosphoryl-1,3,4(3H)-thiadiazol-2-ones. read more here.
Keywords: phosphoryl substituted; substituted thiadiazolones; phosphoryl; synthesis phosphoryl ... See more keywords
Coordination mode of the N-[bis(diethylamino)phosphoryl]benzenesulfonamide ligand in Lu(III) and Ag(I) complexes. Mass spectra, thermal properties and DFT calculations
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2017.09.038
Abstract: Abstract The sulfonylamidophosphate ligand C6H5SO2NHPO(N(C2H5)2)2 (HL) has been used for the synthesis of two novel complexes: LuL3 (1) and (AgL)n (2). According to an X-ray diffraction study, in the structure of HL, the molecules are… read more here.
Keywords: coordination mode; dft calculations; mode bis; ligand ... See more keywords
Lewis Acid Enables Ketone Phosphorylation to Form a C-P Bond and a C-C Bond: Synthesis of 9-Phosphoryl Fluorene Derivatives.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c02504
Abstract: An efficient method for the Lewis acid promotion of the synthesis 9-phosphoryl fluorenes has been reported. This method focuses on ketone phosphonylation to form a C-P bond and a C-C bond between diphenylmethanone and H-phosphinate… read more here.
Keywords: lewis acid; bond; form bond; synthesis phosphoryl ... See more keywords
Phosphoryl-Ligand Adducts of Rare Earth-TriNOx Complexes: Systematic Studies and Implications for Separations Chemistry
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b05638
Abstract: Phosphoryl ligands of the general formula O═PR3 (R = Me, OMe, Et, nBu, Ph, iPr, NMe2) were coordinated to [Nd(TriNOx)] (TriNOx3– = ([(2-tBuNO)C6H4CH2]3N)3–), and the resulting complexes were characterized. Solution equilibrium constants for each complex… read more here.
Keywords: phosphoryl ligand; phosphoryl ligands; chemistry; rare earth ... See more keywords
On the Origins of Enzymes: Phosphate-Binding Polypeptides Mediate Phosphoryl Transfer to Synthesize Adenosine Triphosphate
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08636
Abstract: Reactions involving the transfer of a phosphoryl (−PO32–) group are fundamental to cellular metabolism. These reactions are catalyzed by enzymes, often large and complex, belonging to the phosphate-binding loop (P-loop) nucleoside triphosphatase (NTPase) superfamily. Due… read more here.
Keywords: phosphate binding; transfer; synthesize adenosine; phosphoryl transfer ... See more keywords