Protein Spin Labeling with a Photocaged Nitroxide Using Diels–Alder Chemistry†
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DOI: 10.1002/cbic.201900318
Abstract: EPR spectroscopy of diamagnetic bio‐macromolecules is based on site‐directed spin labeling (SDSL). Herein, a novel labeling strategy for proteins is presented. A nitroxide‐based spin label has been developed and synthesized that can be ligated to… read more here.
Keywords: photocaged nitroxide; diels alder; chemistry; labeling photocaged ... See more keywords