The Merger of Benzophenone HAT Photocatalysis and Silyl Radical-Induced XAT Enables Both Nickel-Catalyzed Cross-Electrophile Coupling and 1,2-Dicarbofunctionalization of Olefins
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DOI: 10.1021/acscatal.2c03805
Abstract: A strategy for both cross-electrophile coupling and 1,2-dicarbofunctionalization of olefins has been developed. Carbon-centered radicals are generated from alkyl bromides by merging benzophenone hydrogen atom transfer (HAT) photocatalysis and silyl radical-induced halogen atom transfer (XAT)… read more here.
Keywords: coupling dicarbofunctionalization; photocatalysis silyl; dicarbofunctionalization olefins; electrophile coupling ... See more keywords