Photocatalytic C-Si Bond Formations Using Pentacoordinate Silylsilicates as Silyl Radical Precursors: Synthetic Tricks Using Old Reagents.
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DOI: 10.1021/acs.orglett.3c00096
Abstract: A visible-light-induced photocatalytic C-Si formation strategy has been disclosed by uncovering the reactivity of Martin's spirosilane-derived pentacoordinate silylsilicates as silyl radical precursors. The hydrosilylation of a broad spectrum of alkenes and alkynes, as well as… read more here.
Keywords: photocatalytic bond; silylsilicates silyl; pentacoordinate silylsilicates; radical precursors ... See more keywords