PPh3/NaI driven photocatalytic decarboxylative radical cascade alkylarylation reaction of 2-isocyanobiaryls
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DOI: 10.1039/d0ra03211e
Abstract: The first triphenylphosphine/sodium iodide driven photocatalytic decarboxylative cascade cyclization of 2-isocyano-biaryls with alkyl N-hydroxyphthalimide (NHP) esters was developed. This operationally simple protocol results in multiple carbon–carbon bond formation under transition metal free conditions, affording a… read more here.
Keywords: nai driven; photocatalytic decarboxylative; driven photocatalytic; pph3 nai ... See more keywords
Recent Advances in Photocatalytic Decarboxylative Coupling Reactions in Medicinal Chemistry
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DOI: 10.1055/s-0039-1690843
Abstract: This review covers recent advances in decarboxylative photocatalysis applicable to the medicinal chemist. The review is not intended to be exhaustive, but instead is focussed on transformations that could be useful in the synthesis of… read more here.
Keywords: coupling reactions; photocatalytic decarboxylative; chemistry; decarboxylative coupling ... See more keywords