Photocatalytic Decarboxylative Heck-Type Postpolymerization Modification of Polyacrylates.
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DOI: 10.1021/acsmacrolett.5c00115
Abstract: Postpolymerization modification of commodity polymers has emerged as a powerful strategy for synthesizing functional polymers that are challenging to obtain via direct polymerization. Moreover, it offers opportunities to upcycle existing polymers and enhance their material… read more here.
Keywords: postpolymerization modification; decarboxylative heck; photocatalytic decarboxylative; heck type ... See more keywords
PPh3/NaI driven photocatalytic decarboxylative radical cascade alkylarylation reaction of 2-isocyanobiaryls
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DOI: 10.1039/d0ra03211e
Abstract: The first triphenylphosphine/sodium iodide driven photocatalytic decarboxylative cascade cyclization of 2-isocyano-biaryls with alkyl N-hydroxyphthalimide (NHP) esters was developed. This operationally simple protocol results in multiple carbon–carbon bond formation under transition metal free conditions, affording a… read more here.
Keywords: nai driven; photocatalytic decarboxylative; driven photocatalytic; pph3 nai ... See more keywords
Recent Advances in Photocatalytic Decarboxylative Coupling Reactions in Medicinal Chemistry
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DOI: 10.1055/s-0039-1690843
Abstract: This review covers recent advances in decarboxylative photocatalysis applicable to the medicinal chemist. The review is not intended to be exhaustive, but instead is focussed on transformations that could be useful in the synthesis of… read more here.
Keywords: coupling reactions; photocatalytic decarboxylative; chemistry; decarboxylative coupling ... See more keywords