Reactive Deposition Versus Strong Electrostatic Adsorption (SEA): A Key to Highly Active Single Atom co-Catalysts in Photocatalytic H2 Generation.
Sign Up to like & getrecommendations! Published in 2023 at "Advanced materials"
DOI: 10.1002/adma.202211814
Abstract: In recent years, the use of single atoms (SAs) has become of a rapidly increasing significance in photocatalytic H2 generation; here SA noble metals (mainly Pt SAs) can act as highly effective co-catalysts. The classic… read more here.
Keywords: adsorption; deposition; electrostatic adsorption; sea ... See more keywords
Photocatalytic generation of hydrogen coupled with in-situ hydrogen storage
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.02.221
Abstract: Abstract To date, hydrogen generation and storage are two separated processes. We report on a new concept where photocatalytically generated hydrogen is simultaneously stored in-situ within the material photo-generating hydrogen. To this aim, we successfully… read more here.
Keywords: hydrogen; storage; generation hydrogen; photocatalytic generation ... See more keywords
Co-catalyst-free ZnS-SnS2 porous nanosheets for clean and recyclable photocatalytic H2 generation
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Alloys and Compounds"
DOI: 10.1016/j.jallcom.2018.04.086
Abstract: Abstract Two-dimensional (2D) ZnS-SnS2 porous nanosheets are designed as clean and low cost photocatalysts for water splitting. The composites successfully combine high photoelectron reduction potential of ZnS with the sufficient sunlight harvesting ability of SnS2.… read more here.
Keywords: sns2; photocatalytic generation; porous nanosheets; zns sns2 ... See more keywords
Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C–C Bond Formations
Sign Up to like & getrecommendations! Published in 2020 at "Accounts of Chemical Research"
DOI: 10.1021/acs.accounts.0c00620
Abstract: Conspectus The use of photocatalysis in organic chemistry has encountered a surge of novel transformations since the start of the 21st century. The majority of these transformations are driven by the generation and subsequent reaction… read more here.
Keywords: photocatalytic generation; strategies photocatalytic; carbanion; generation ... See more keywords
Multi-Electron Visible Light Photoaccumulation on a Dipyridylamine Copper(II)-Polyoxometalate Conjugate Applied to Photocatalytic Generation of CF3 Radicals.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01716
Abstract: This article describes the synthesis and characterization of an organic-inorganic hybrid polyoxometalate functionalized by a short link with a tripodal N-based ligand and its copper complex. Upon visible light irradiation, the latter is able to… read more here.
Keywords: generation cf3; copper; cf3 radicals; polyoxometalate ... See more keywords
A microporous mixed-metal (Na/Cu) mixed-ligand (flexible/rigid) metal–organic framework for photocatalytic H2 generation
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry C"
DOI: 10.1039/c9tc03342d
Abstract: This work presents a cost-effective mixed-metal mixed-ligand MOF, which exhibits highly efficient photocatalytic H2 generation under visible-light irradiation. read more here.
Keywords: metal; mixed ligand; mixed metal; metal mixed ... See more keywords
Simultaneous photocatalytic H2 generation and organic synthesis over crystalline-amorphous Pd nanocube decorated Cs3Bi2Br9.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02453e
Abstract: Cs3Bi2Br9 decorated with crystalline-amorphous Pd nanocubes as cocatalysts is reported to photocatalytically coproduce ca. 1400 μmol h-1 g-1 of H2 and benzaldehyde from the selective benzyl alcohol oxidation. This route offers an alternative for photocatalytic… read more here.
Keywords: cs3bi2br9; simultaneous photocatalytic; crystalline amorphous; generation organic ... See more keywords