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   Articles with "photochemical activation" as a keyword



Photochemical C−H Activation: An Early Story

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recommendations! Published in 2017 at "Israel Journal of Chemistry"

DOI: 10.1002/ijch.201700046

Abstract: An early investigation in the author‘s laboratory into photochemical C−H bond activation and functionalization is recounted. Specifically, d8 Ir(I) and Rh(I) carbonyl phosphine complexes were found to promote benzene C−H bond activtion and functionalization to… read more here.

Keywords: photochemical activation; activation early; early story; benzene ... See more keywords

In Situ Photochemical Activation of Sulfate for Enhanced Degradation of Organic Pollutants in Water.

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recommendations! Published in 2017 at "Environmental science & technology"

DOI: 10.1021/acs.est.6b05090

Abstract: The advanced oxidation process (AOP) based on SO4•- radicals has been receiving growing attention in water and wastewater treatment. Producing SO4•- radicals by activation of peroxymonosulfate or persulfate faces the challenges of high operational cost… read more here.

Keywords: situ photochemical; photochemical activation; sulfate; water ... See more keywords

Shedding Light on Photochemical Activation and Catalytic Mechanism of Cobalt-Catalyzed Alkene Hydroaminocarbonylation

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recommendations! Published in 2025 at "ACS Catalysis"

DOI: 10.1021/acscatal.5c05161

Abstract: In a recent experimental study, a cobalt-catalyzed, light-induced synthesis of amides, achieving 100% atom economy by coupling amines and alkenes under 390 nm LED illumination, was reported. Despite its practical appeal, important mechanistic questions remain,… read more here.

Keywords: photochemical activation; activation; cobalt catalyzed; mechanism ... See more keywords

Photochemical activation of pincer-ligated phosphoranides: mechanistic insight for reduction of aryl halides.

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recommendations! Published in 2025 at "Chemical science"

DOI: 10.1039/d5sc06960b

Abstract: Pincer-ligated phosphoranides constitute a relatively underexplored subclass of main-group compounds whose distinctive structural and electronic properties are now attracting renewed interest. In this study, we report the synthesis, full characterization, and novel photoreactivity of O,N,O-pincer… read more here.

Keywords: aryl halides; photochemical activation; pincer; activation pincer ... See more keywords