Photochemical hydrogen evolution from cobalt microperoxidase-11.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2021.111384
Abstract: A photochemical system utilizing the semisynthetic biomolecular catalyst acetylated cobalt microperoxidase-11 (CoMP11-Ac) along with [Ru(bpy)3]2+ as a photosensitizer and ascorbic acid as an electron donor is shown to generate hydrogen from water in a visible… read more here.
Keywords: cobalt microperoxidase; hydrogen evolution; evolution cobalt; photochemical hydrogen ... See more keywords
Photochemical hydrogen evolution from water by a 1D-network of octahedral Ni6L8 cages.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc06286f
Abstract: A self-assembled M6L8 type cage-connected 1D-coordination network of formula {[Ni6(MeSi(3py)3)8Cl9(H2O)2]Cl3·16H2O}∞ (1) was obtained from a 3-pyridyl substituted silane ligand MeSi(3py)3. This complex shows significantly high performance for the electrocatalytic and photocatalytic hydrogen evolution reaction (HER)… read more here.
Keywords: water; photochemical hydrogen; hydrogen evolution; network ... See more keywords
Resurgence and advancement of photochemical hydrogen atom transfer processes in selective alkane functionalizations
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc01118f
Abstract: By drawing inspiration from photoredox catalysis, the field of radical-mediated alkane functionalization has made remarkable advancements recently to address the challenges of today and future. read more here.
Keywords: hydrogen atom; photochemical hydrogen; resurgence advancement; atom transfer ... See more keywords