Unexpected photochemical transformation of imidazole derivatives containing the 5-hydroxy-2-methyl-4H-pyran-4-one moiety. Environmentally friendly method for the synthesis of substituted imidazo[1,5-a]pyridine-5,8-diones
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.151080
Abstract: Abstract An unexpected photochemical transformation of imidazole derivatives containing the 5-hydroxy-2-methyl-4H-pyran-4-one moiety was discovered, which led to the synthesis of previously unknown imidazo[1,5-a]pyridine-5,8-dione derivatives. The structures of imidazole and imidazo[1,5-a]pyridine-5,8-dione derivatives were unambiguously determined by… read more here.
Keywords: imidazo pyridine; unexpected photochemical; photochemical transformation; transformation imidazole ... See more keywords
Simulation of photoreactive transients and of photochemical transformation of organic pollutants in sunlit boreal lakes across 14 degrees of latitude: A photochemical mapping of Sweden.
Sign Up to like & getrecommendations! Published in 2018 at "Water research"
DOI: 10.1016/j.watres.2017.10.064
Abstract: Lake water constituents, such as chromophoric dissolved organic matter (CDOM) and nitrate, absorb sunlight which induces an array of photochemical reactions. Although these reactions are a substantial driver of pollutant degradation in lakes they are… read more here.
Keywords: organic pollutants; photochemical transformation; transformation organic; lakes across ... See more keywords
Development of Fluorescence Surrogates to Predict the Photochemical Transformation of Pharmaceuticals in Wastewater Effluents.
Sign Up to like & getrecommendations! Published in 2017 at "Environmental science & technology"
DOI: 10.1021/acs.est.6b05251
Abstract: The photochemical transformation of pharmaceutical and personal care products (PPCPs) in wastewater effluents is an emerging concern for environmental scientists. In the current study, the photodegradation of 29 PPCPs was examined in effluents under simulated… read more here.
Keywords: photochemical transformation; photodegradation; fluorescence; ppcps ... See more keywords
Effects of a redox-active diketone on the photochemical transformation of roxarsone: Mechanisms and environmental implications.
Sign Up to like & getrecommendations! Published in 2022 at "Chemosphere"
DOI: 10.2139/ssrn.4173896
Abstract: Organoarsenical antibiotics pose a severe threat to the environment and human health. In aquatic environment, dissolved organic matter (DOM)-mediated photochemical transformation is one of the main processes in the fate of organoarsenics. Dicarbonyl is a… read more here.
Keywords: diketone; environment; redox active; photochemical transformation ... See more keywords