Spectroscopic Investigation of Interaction between the 4f Electronic System and the Photoexcited Cyclic π System in Terbium(III) Monoporphyrinato Complex.
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DOI: 10.1021/acs.inorgchem.0c02107
Abstract: Electronic interaction between the total angular momentum (J) of the 4f electronic system and an angular momentum (L) of the photoexcited cyclic π system in a terbium(III) monoporphyrinato complex with a capping ligand cyclen, [Tb(TPP)(cyclen)]Cl… read more here.
Keywords: cyclic system; system; angular momentum; electronic system ... See more keywords
Antiparallel Coupling between a 4f System and a Photoexcited Cyclic π System in a Dysprosium(III) Monoporphyrinato Complex.
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DOI: 10.1021/acs.inorgchem.1c02199
Abstract: Magnetic coupling resulted by an orbital angular momentum L of a photoexcited cyclic π-conjugated system and total angular momentum J of a localized 4f electronic system in [Dy(TPP)(cyclen)]Cl (TPP = 5,10,15,20-tetraphenylporphyrinato; cyclen = 1,4,7,10-tetraazacyclododecane) has… read more here.
Keywords: cyclic system; system; system photoexcited; coupling system ... See more keywords