Solvent Anions Enable Photoinduced Borylation and Phosphonation of Aryl Halides via EDA Complexes.
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DOI: 10.1021/acs.orglett.2c02631
Abstract: We report the synthesis of aryl boronic esters and aryl phosphonate esters promoted by visible-light in the absence of transition-metals or photoredox catalysts. The transformation proceeds at room temperature using sodium hydride, as a non-nucleophilic… read more here.
Keywords: enable photoinduced; aryl halides; eda; photoinduced borylation ... See more keywords