Stereoselective Synthesis of Monofluoroalkenylphosphine Oxides via Photoinduced Decarboxylative Coupling of α-Fluoroacrylic Acids with P(O)H Compounds.
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DOI: 10.1021/acs.orglett.3c00631
Abstract: Herein, a practical and efficient method for synthesizing monofluoroalkenyl phosphine oxides via photoinduced decarboxylative/dehydrogenative coupling of α-fluoroacrylic acids with phosphine oxides and phosphonates has been developed. Various α-fluoroacrylic acids and P(O)H compounds containing relevant functional… read more here.
Keywords: fluoroacrylic acids; oxides via; via photoinduced; coupling fluoroacrylic ... See more keywords
Photoinduced decarboxylative borylation of carboxylic acids
Sign Up to like & getrecommendations! Published in 2017 at "Science"
DOI: 10.1126/science.aan3679
Abstract: Lighting the way to carbon borylation Boron substituents provide versatile reactivity, and their utility has been emerging in pharmaceutical contexts. Fawcett et al. show that visible light can induce replacement of carboxylic acid groups with… read more here.
Keywords: methodology; borylation; carboxylic acids; borylation carboxylic ... See more keywords