Photoinduced Defluorinative Branch-Selective Olefination of Multifluoro (Hetero)arenes.
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DOI: 10.1021/acs.orglett.3c00115
Abstract: We report a photoredox platform for constructing styrenyl polyfluoro (hetero)arenes with branch selectivity by taking advantage of sulfinate as both a radical-relay precursor and a sacrificial nucleofuge. This protocol merges photoredox catalysis with radical-radical coupling… read more here.
Keywords: hetero; defluorinative branch; photoinduced defluorinative; branch selective ... See more keywords