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Published in 2019 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2018.11.011
Abstract: Abstract Photoinduced reversible intramolecular hydrogen-atom migration between 9H-fluorene and 1H-fluorene isolated in an Ar matrix is found by FTIR spectroscopy with an aid of DFT calculation. The forward isomerization from 9H-fluorene to 1H-fluorene occurs upon…
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Keywords:
fluorene;
spectroscopy;
hydrogen atom;
fluorene fluorene ... See more keywords
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Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.04.036
Abstract: Abstract 2-Phenyl-1,3-di(4-pyridyl)naphthvalene 3a was synthesized by the photoinduced reversible valence isomerization of 2-phenyl-1,3-di(4-pyridyl)naphthalene 2a. Then, 3a was converted into 3-phenyl-1,2-di(4-pyridyl)naphthalene 4a and 2a simultaneously. The t1/2 of 3a in DMSO-d6 at 90 °C was 2 h, while…
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Keywords:
pyridyl;
phenyl pyridyl;
pyridyl naphthalene;
pyridyl naphthvalene ... See more keywords