Photoinduced Single Electron Reduction of the 4‐O‐5 Linkage in Lignin Models for C‐P Coupling Catalyzed by Bifunctional N‐Heterocyclic Carbenes
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Science"
DOI: 10.1002/advs.202406095
Abstract: Catalytic activation of Caryl‐O bonds is considered as a powerful strategy for the production of aromatics from lignin. However, due to the high reduction potentials of diaryl ether 4‐O‐5 linkage models, their single electron reduction… read more here.
Keywords: bifunctional heterocyclic; photoinduced single; single electron; reduction ... See more keywords
Photoinduced Single Electron Transfer via EDA Complexation Enables Decarbonylative C(sp2)-S Bond Formation.
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DOI: 10.1021/acs.orglett.4c03910
Abstract: We have developed a photoinduced transition-metal-free decarbonylative strategy at ambient temperature through non-covalent interactions to achieve vinyl sulfones. Traditionally, decarbonylative functionalization is accomplished using transition metal catalysts at elevated temperatures. The π-π interaction facilitates the… read more here.
Keywords: transfer via; electron transfer; photoinduced single; eda complexation ... See more keywords
Photoinduced single unit monomer insertion promoted by deep eutectic solvents
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DOI: 10.1039/d5py00848d
Abstract: Deep eutectic solvent (DES) enables photoinduced single unit monomer insertion (SUMI) with a high reaction rate, high selectivity, and improved oxygen tolerance. read more here.
Keywords: monomer insertion; deep eutectic; photoinduced single; single unit ... See more keywords