Preparing Well-Defined Polyacrylamide-b-Polycarbonate by Integrating Photoiniferter Polymerization and TBD-Catalyzed ROP.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200376
Abstract: The dual-initiator technique allows the polymerization of different monomers from orthogonal polymerization mechanisms to obtain block copolymers (BCPs). In this study, we attempted to combine photoiniferter living free radical polymerization and organocatalytic ring-opening polymerization (ROP)… read more here.
Keywords: well defined; rop; photoiniferter; preparing well ... See more keywords
Assembly of a visible light photoreactor: an inexpensive tool for bottlebrush polymer synthesis via photoiniferter polymerization
Sign Up to like & getrecommendations! Published in 2017 at "Polymer Chemistry"
DOI: 10.1039/c7py01741c
Abstract: Here we report the design of a simple, inexpensive photoreactor for photoiniferter polymerization of vinyl monomers mediated by thiocarbonylthio compounds. A trithiocarbonate photoiniferter activated by blue light allowed for the synthesis of homopolymers and block… read more here.
Keywords: bottlebrush; synthesis; photoreactor; photoiniferter ... See more keywords