Formation of highly crosslinked polymer films in the presence of bio-based epoxy by photoinitiated cationic polymerization
Sign Up to like & getrecommendations! Published in 2021 at "Progress in Organic Coatings"
DOI: 10.1016/j.porgcoat.2021.106377
Abstract: Abstract Oleic acid was used as bio-based starting material for manufacturing of bis-(9,10-epoxystearic acid) 1,2-ethanediyl ester (EEDE). In contrast to epoxidized triglycerides, which contain also saturated structures, EEDE comprises exactly two epoxy groups that is… read more here.
Keywords: dgeba; bio based; photoinitiated cationic; eede dgeba ... See more keywords
Molecular Origin of the Induction Period in Photoinitiated Cationic Polymerization of Epoxies and Oxetanes
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.8b02486
Abstract: We investigated how the reactivity of epoxide and oxetane monomers in photoinitiated cationic polymerization is strongly influenced by their ability to form intramolecular hydrogen-bonding complexes with the Bronsted acids produced by the photoinitiator. In this… read more here.
Keywords: photoinitiated cationic; induction period; cationic polymerization;
Photoinitiated Cationic Ring-Opening Polymerization of Octamethylcyclotetrasiloxane
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28031299
Abstract: Photochemical techniques have recently been revitalized as they can readily be adapted to different polymerization modes to yield a wide range of complex macromolecular structures. However, the implementation of the photoinduced cationic methods in the… read more here.
Keywords: opening polymerization; cationic ring; ring opening; photoinitiated cationic ... See more keywords