Articles with "photooxidation" as a keyword



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Single‐Component‐Based White Light Photoluminescence Emission via Selective Photooxidation in an Organic–Polymer Hybrid System

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Published in 2018 at "Advanced Functional Materials"

DOI: 10.1002/adfm.201703509

Abstract: White light-emitting phenothiazine-poly(dimethylsiloxane) (PTZ–PDMS) composites are formed by a photooxidation reaction. The oxidized PTZ species, i.e., PTZ cation radicals and dication species, are created by electron transfer from the PTZ molecules to PDMS under UV… read more here.

Keywords: ptz; component based; single component; photooxidation ... See more keywords

Quercetin and cyanidin‐3‐glucoside protect against photooxidation and photodegradation of A2E in retinal pigment epithelial cells

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Published in 2017 at "Experimental Eye Research"

DOI: 10.1016/j.exer.2017.04.010

Abstract: &NA; A family of photoreactive retinaldehyde‐derived molecules accumulate in retinal pigment epithelial cells with age; this accumulation is implicated in some retinal diseases. One of these compounds is the diretinal fluorophore A2E. Here we compared… read more here.

Keywords: cyanidin glucoside; photooxidation; quercetin cyanidin;
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Competing pathways of cresol formation in toluene photooxidation: OH-toluene adducts react with NO2 or with O2?

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Published in 2022 at "Journal of environmental sciences"

DOI: 10.1016/j.jes.2021.08.036

Abstract: Methyl-hydroxy-cyclohexadienyl radicals (OTAs) are the key products of the photooxidation of toluene, with implications for the fate of toluene. Hence, we investigated the photooxidation mechanisms and kinetics of three main OTAs (o-OTA, m-OTA, and p-OTA)… read more here.

Keywords: ota no2; photooxidation toluene; anti abstraction; toluene ... See more keywords
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Probing reactions between imipramine and hydroxyl radical with the photolysis of iron(III) oxalate: Implications for the indirect photooxidation of tricyclic antidepressants in waters

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Published in 2022 at "Journal of Photochemistry and Photobiology A: Chemistry"

DOI: 10.1016/j.jphotochem.2021.113559

Abstract: Abstract Photodegradation of imipramine (IMI), a widely used tricyclic antidepressant, in the presence of Fe(III) oxalate and potassium persulfate (PS) was studied for the first time by combination of steady state and laser flash photolysis.… read more here.

Keywords: iii; photolysis; hydroxyl radical; iii oxalate ... See more keywords
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Prooxidant activity of phenolic stabilizers in polyolefins during accelerated photooxidation

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Published in 2019 at "Polymer Degradation and Stability"

DOI: 10.1016/j.polymdegradstab.2019.06.013

Abstract: Abstract Polymer plaques made of high density polyethylene (HDPE) and of two types of cycloolefin copolymer (COC) differing in glass transition temperature, were stabilized with 0.2 or 1.0 wt % of natural (α-tocopherol) or synthetic (Irganox… read more here.

Keywords: phenolic stabilizers; prooxidant activity; photooxidation; activity phenolic ... See more keywords
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In situ biodegradation, photooxidation and dissolution of petroleum compounds in Arctic seawater and sea ice.

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Published in 2019 at "Water research"

DOI: 10.1016/j.watres.2018.10.066

Abstract: In pristine sea ice-covered Arctic waters the potential of natural attenuation of oil spills has yet to be uncovered, but increasing shipping and oil exploitation may bring along unprecedented risks of oil spills. We deployed… read more here.

Keywords: sea ice; biodegradation; photooxidation; ice ... See more keywords
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Monoterpene Photooxidation in a Continuous-Flow Chamber: SOA Yields and Impacts of Oxidants, NOx, and VOC Precursors.

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Published in 2022 at "Environmental science & technology"

DOI: 10.1021/acs.est.2c02630

Abstract: Monoterpene photooxidation plays an important role in secondary organic aerosol (SOA) formation in the atmosphere. The low-volatility products can enhance new particle formation and particle growth and thus influence climate feedback. Here, we present the… read more here.

Keywords: photooxidation; chamber; monoterpene photooxidation; continuous flow ... See more keywords
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Impact of Photooxidation and Biodegradation on the Fate of Oil Spilled During the Deepwater Horizon Incident: Advanced Stages of Weathering.

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Published in 2017 at "Environmental science & technology"

DOI: 10.1021/acs.est.7b01278

Abstract: While the biogeochemical forces influencing the weathering of spilled oil have been investigated for decades, the environmental fate and effects of "oxyhydrocarbons" in sand patties deposited on beaches are not well-known. We collected sand patties… read more here.

Keywords: biodegradation; photooxidation; deepwater horizon; sand patties ... See more keywords
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Boosted Activity for Toluene Selective Photooxidation over Fe-Doped Bi2WO6

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Published in 2020 at "Industrial & Engineering Chemistry Research"

DOI: 10.1021/acs.iecr.0c02872

Abstract: Selective photooxidation of toluene to benzaldehyde using O2 as an oxidant has the advantages of mild reaction conditions and excellent atomic economy, but it often suffers from low conversion effi... read more here.

Keywords: selective photooxidation; photooxidation; activity toluene; boosted activity ... See more keywords
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Lanthanide-Anderson Polyoxometalates Frameworks: Efficient Sulfide Photooxidation.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c03504

Abstract: Three polyoxometalate-based metal-organic frameworks were synthesized by the thermal reaction of pyridyl-Anderson polyoxometalate linker and lanthanide ions. With the help of [Ru(bpy)3]2+ photosensitizer, these frameworks exhibited excellent photocatalytic sulfide oxidation performance with sulfoxide selectivity. The… read more here.

Keywords: photooxidation; frameworks efficient; lanthanide anderson; anderson ... See more keywords
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Indolizines Enabling Rapid Uncaging of Alcohols and Carboxylic Acids by Red Light-Induced Photooxidation.

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Published in 2020 at "Organic letters"

DOI: 10.1021/acs.orglett.0c01799

Abstract: The irradiation of red light-emitting-diode light (λ = 660 nm) to 3-acyl-2-methoxyindolizines in the presence of a catalytic amount of methylene blue triggered the photooxidation of the indolizine ring, resulting in a nearly quantitative release… read more here.

Keywords: carboxylic acids; red light; indolizines enabling; enabling rapid ... See more keywords