Excitation-Wavelength-Dependent Photophysics of d8d8 Di-isocyanide Complexes.
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DOI: 10.1021/acs.inorgchem.1c02645
Abstract: Binuclear Rh(I) and Ir(I) TMB (2,5-dimethyl-2,5-diisocyanohexane) and dimen (1,8-diisocyanomenthane) complexes possess dσ*pσ and dπpσ singlet and triplet excited states that can be selectively excited in the visible and UV spectral regions. Using perturbational spin-orbit TDDFT,… read more here.
Keywords: excitation wavelength; wavelength dependent; photophysics d8d8; excitation ... See more keywords