Metal‐Semiconductor Heterostructures for Photoredox Catalysis: Where Are We Now and Where Do We Go?
Sign Up to like & getrecommendations! Published in 2021 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202101103
Abstract: The ability of metal nanocrystals (NCs) to maneuver light, trap charge carriers, and enrich reactive sites for photoredox reactions has received considerable attention for constructing metal‐semiconductor heterostructures (MSHs) toward solar‐to‐chemical production. In this review, the… read more here.
Keywords: semiconductor heterostructures; catalysis; photoredox catalysis; metal semiconductor ... See more keywords
Mitochondria‐Targeted Photoredox Catalysis Activates Pyroptosis for Effective Tumor Therapy
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202417681
Abstract: The development of biocompatible and efficient photocatalytic redox systems to mimic bio‐photoreactors in living cells holds great potential for manipulating intracellular biochemical reaction processes and thus advancing tumor therapy. In this study, a mitochondria‐targeted photoredox… read more here.
Keywords: tumor therapy; mitochondria targeted; tumor; targeted photoredox ... See more keywords
Maneuvering Charge Transport via Insulating Polymer Interface for Steering Photoredox Catalysis
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Science"
DOI: 10.1002/advs.202507670
Abstract: Maneuvering precise and tunable charge transportation has remained the core issue of photocatalysis, but meets with limited success owing to the ultra‐fast charge recombination rate, scarcity of applicable co‐catalysts, and difficulty in customizing spatially separated… read more here.
Keywords: transport; charge transport; interface; charge ... See more keywords
Effects of Lewis Acids on Photoredox Catalysis
Sign Up to like & getrecommendations! Published in 2017 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.201600576
Abstract: The reactivity of organic photoredox catalysts in oxidation reactions is enhanced by the addition of Lewis acids, which bind to the catalyst to increase its oxidizing ability. Redox-inactive metal ions, such as Sc3+, also act… read more here.
Keywords: effects lewis; chemistry; lewis acids; acids photoredox ... See more keywords
Aerobic Oxidation of Alkynes to 1,2‐Diketones by Organic Photoredox Catalysis
Sign Up to like & getrecommendations! Published in 2017 at "ChemCatChem"
DOI: 10.1002/cctc.201700061
Abstract: A method for the synthesis of 1,2‐diketones through the mild and metal‐free catalytic photooxygenation of alkynes is described. This reaction, using 9,10‐dicyanoanthracene as a catalytic sensitizer with/without biphenyl as a co‐sensitizer, readily furnished a variety… read more here.
Keywords: diketones organic; alkynes diketones; aerobic oxidation; organic photoredox ... See more keywords
Radical Aromatic Trifluoromethylthiolation: Photoredox Catalysis vs. Base Mediation
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201701339
Abstract: Trifluoromethyl aryl sulfides (Ar-SCF3) constitute highly attractive building blocks due to their exceptional lipophilicity and chemical properties. Related protocols of radical aromatic trifluoro-methylthiolation of arenediazonium salts were developed that are based on the facile generation… read more here.
Keywords: radical aromatic; photoredox catalysis; base; aromatic trifluoromethylthiolation ... See more keywords
Asymmetric Organocatalysis and Photoredox Catalysis for the α‐Functionalization of Tetrahydroisoquinolines
Sign Up to like & getrecommendations! Published in 2018 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201800117
Abstract: H. H. and S. Z. are grateful to the Chinese Scholarship Council for fellowships. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme… read more here.
Keywords: functionalization tetrahydroisoquinolines; asymmetric organocatalysis; chemistry; organocatalysis photoredox ... See more keywords
A review of enantioselective dual transition metal/photoredox catalysis
Sign Up to like & getrecommendations! Published in 2020 at "Science China Chemistry"
DOI: 10.1007/s11426-019-9701-5
Abstract: Transition metal catalysis is one of the most important tools to construct carbon-carbon and carbon-heteroatom bonds in modern organic synthesis. Visible-light photoredox catalysis has recently drawn considerable attention of the scientific community owing to its… read more here.
Keywords: transition metal; photoredox catalysis; chemistry; catalysis ... See more keywords
N-substituted-3(10H)-acridones as visible-light photosensitizers for organic photoredox catalysis
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron"
DOI: 10.1016/j.tet.2017.12.019
Abstract: Abstract N-Substituted-3(10H)-acridones have been established as visible-light organic photocatalyst. These photosensitizers are efficient for oxidative coupling reaction of N-aryl tetrahydroisoquinolines with various nucleophiles. Notably, N-methyl-3(10H)-acridone (Ia) is stable and can be effectively prepared. It is… read more here.
Keywords: substituted 10h; visible light; acridones visible; 10h acridones ... See more keywords
Bioinspired Supercharging of Photoredox Catalysis for Applications in Energy and Chemical Manufacturing.
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00083
Abstract: ConspectusFor more than a decade, photoredox catalysis has been demonstrating that when photoactive catalysts are irradiated with visible light, reactions occur under milder, cheaper, and environmentally friendlier conditions. Furthermore, this methodology allows for the activation… read more here.
Keywords: chemical manufacturing; photoredox catalysis; chemistry; energy ... See more keywords
Fluorinated Radicals in Divergent Synthesis via Photoredox Catalysis
Sign Up to like & getrecommendations! Published in 2025 at "Accounts of Chemical Research"
DOI: 10.1021/acs.accounts.5c00239
Abstract: Conspectus Fluorine is an essential element in pharmaceuticals, agrochemicals, and material sciences, significantly enhancing the bioactivity, metabolic stability, and physicochemical properties of organic molecules. In medicinal chemistry, nearly 20% of marketed drugs contain at least… read more here.
Keywords: chemistry; divergent synthesis; synthesis; fluorine ... See more keywords