Sign Up to like & get
recommendations!
1
Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03894
Abstract: The construction of molecular skeletons and modification of molecules using widely available and easily prepared alcohols as radical precursors for coupling reactions are significant and challenging subjects. We herein report a straightforward strategy for the…
read more here.
Keywords:
opening alkenylation;
cobalt catalysis;
dual photoredox;
alkenylation cycloalkanols ... See more keywords
Sign Up to like & get
recommendations!
1
Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c00527
Abstract: We demonstrate Markovnikov hydroalkoxylation of unactivated alkenes using alcohols through a triple catalysis consisting of photoredox, cobalt, and Brønsted acid catalysts under visible light irradiation. The triple catalysis realizes three key elementary steps in a…
read more here.
Keywords:
catalysis;
hydroalkoxylation unactivated;
markovnikov hydroalkoxylation;
photoredox cobalt ... See more keywords
Sign Up to like & get
recommendations!
1
Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03595b
Abstract: An enantioselective ortho-C(sp2)-H functionalization of ketones with 1,6-enynes is demonstrated via photoredox/cobalt dual catalysis. The method exhibits high yields, functional group tolerance, and selectivity. Mechanistic studies suggested the operation of visible-light mediated low-valent cobalt complex…
read more here.
Keywords:
cobalt;
via photoredox;
ketones enynes;
dual catalysis ... See more keywords