A Substrate-Binding Metal-Organic Layer Selectively Catalyzes Photoredox Ene-Carbonyl Reductive Coupling Reactions.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c10180
Abstract: Intermolecular photoredox ene-carbonyl reductive coupling reactions typically have low product selectivity owing to competing dimerization and/or reduction of ketyl radicals. Herein, we report a metal-organic layer (MOL), Hf-Ir-OTf, as a bifunctional photocatalyst for selective photoredox… read more here.
Keywords: ene carbonyl; coupling; reductive coupling; coupling reactions ... See more keywords