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Photoswitchable Keto-Enol Tautomerism Driven by Light-Induced Change in Antiaromaticity.

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Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c03441

Abstract: The bidirectional interconversion between ketone and enol structures of 4-cyclopentene-1,3-dione derivatives was realized by photoswitching of fused dithienylethene using UV and visible light. A loss of antiaromaticity offered the driving force for light-triggered enolization and… read more here.

Keywords: light induced; enol tautomerism; enol; photoswitchable keto ... See more keywords