Access to β-Lactams via Iron-Catalyzed Olefin Oxyamidation Enabled by the π-Accepting Phthalocyanine Ligand.
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DOI: 10.1021/jacs.1c12125
Abstract: Herein, we report the development of an iron-catalyzed olefin oxyamidation by utilizing tethered dioxazolones as the nitrenoid precursor to produce valuable β-lactam scaffolds. Mechanistic studies revealed that a relatively strong π-accepting ability of the phthalocyanine… read more here.
Keywords: olefin oxyamidation; iron; phthalocyanine ligand; catalyzed olefin ... See more keywords