Piano stool complexes of N-heterocyclic carbene ligands bearing a galactose-derived substituent
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119651
Abstract: Abstract Piano stool complexes of NHC ligands bearing a chiral auxiliary derived from α-ᴅ-galactose, and linked through the C-6 carbon atom, have been synthesized and structurally characterized by single crystal X-ray diffraction. [(η6-C6H3Me3)RuCl2(κC-1,3-MeNC3H2NR)], R = 1,2:3,4-di-O-isopropylidene-6-deoxy-α-D-galactopyran-6-yl, (4)… read more here.
Keywords: piano stool; complexes heterocyclic; ligands bearing; stool complexes ... See more keywords
Ruthenium(II) piano stool coordination compounds with aminomethylphosphanes: Synthesis, characterisation and preliminary biological study in vitro.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2017.02.017
Abstract: Reaction of {[Ru(η6-p-cymene)Cl]2(μ-Cl)2} (1) with aminomethylphosphane derived from morpholine (P{CH2N(CH2CH2)2O}3 (A), PPh2{CH2N(CH2CH2)2O} (B)) or piperazine (P{CH2N(CH2CH2)2NCH2CH3}3 (C), PPh2{CH2N(CH2CH2)2NCH2CH3} (D)) results in four new piano stool ruthenium(II) coordination compounds: [Ru(η6-p-cymene)Cl2(A)] (2A), [Ru(η6-p-cymene)Cl2(B)] (2B), [Ru(η6-p-cymene)Cl2(C)] (2C) and… read more here.
Keywords: coordination compounds; piano stool; ch2n ch2ch2; cymene cl2 ... See more keywords
Synthesis, Characterization, and Light Sensitivity in Titanium Piano Stool Alkyl and Sulfur Complexes, [(C5Me5)TiMe2R] n− (R = Me, SCPh3, S; n = 0, 1)
Sign Up to like & getrecommendations! Published in 2025 at "Organometallics"
DOI: 10.1021/acs.organomet.5c00080
Abstract: The piano stool complex (C5Me5)TiMe3, 1, reacts with HSCPh3 to produce (C5Me5)TiMe2(SCPh3), 2. Reduction of 2 with an alkali metal (K or Na) produces the sulfide complexes [K(crypt)][(C5Me5)TiMe2(S)], 3-K(crypt), and (C5Me5)TiMe2(μ-S)M(18-crown-6), 3-M(18c6) (M = K,… read more here.
Keywords: titanium; c5me5 time2; piano; synthesis characterization ... See more keywords
PM-IRRAS and DFT investigation of the surface orientation of new Ir piano-stool complexes attached to Au(111).
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02730e
Abstract: Surface immobilization of organometallic catalysts is a promising approach to developing new catalytic systems that combine molecular catalysts with heterogenous surfaces to probe surface mechanisms. The orientation of the catalyst relative to the surface is… read more here.
Keywords: irras dft; piano stool; surface; orientation ... See more keywords