Use of Piers–Rubinsztajn Chemistry to Access Unique and Challenging Silicon Phthalocyanines
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DOI: 10.1021/acsomega.1c02738
Abstract: Axial functionalization is one mode that enables the solubility of silicon phthalocyanines (SiPcs). Our group observed that the use of typical axial functionalization methodologies on reaction of Cl2SiPc with the chlorotriphenyl silane reagent unexpectedly resulted… read more here.
Keywords: sipc; chemistry; piers rubinsztajn; silicon ... See more keywords
Scalable Synthetic Route to PDMS Ring Polymers in High Yields from Commercially Available Materials Using the Piers-Rubinsztajn Reaction
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DOI: 10.1021/acsomega.2c05996
Abstract: While cyclic polymers have intrigued researchers for their novel set of architecture-driven rheological interactions, the possibility of incorporating them in topological systems has been limited by the availability of large ring polymers. Thus, the need… read more here.
Keywords: ring polymers; pdms ring; scalable synthetic; synthetic route ... See more keywords
Polymerization of Cyclododecasiloxanes with Si–H and Si–OEt Side Groups by the Piers-Rubinsztajn Reaction
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DOI: 10.1246/bcsj.20170410
Abstract: Two types of cyclododecasiloxanes possessing Si–H and Si–OEt side groups were polymerized by the Piers-Rubinsztajn (P-R) reaction. Cyclododecasiloxane possessing both methyl and ethoxydimethylsilyl side groups (Cyclo12-Me-SiMe2(OEt)) was synthesized by ethoxylation of cyclododecasiloxane possessing both methyl… read more here.
Keywords: piers rubinsztajn; rubinsztajn reaction; reaction; side groups ... See more keywords
Hyperbranched Polycarbosiloxanes: Synthesis by Piers-Rubinsztajn Reaction and Application as Precursors to Magnetoceramics
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DOI: 10.3390/polym12030672
Abstract: Silicon-containing hyperbranched polymers (Si-HBPs) have drawn much attention due to their promising applications. However, the construction of Si-HBPs, especially those containing functional aromatic units in the branched backbones by the simple and efficient Piers-Rubinsztajn (P–R)… read more here.
Keywords: piers rubinsztajn; rubinsztajn reaction; hyperbranched polycarbosiloxanes; bis dimethylsilyl ... See more keywords