Advances in diversified application of pillar[n]arenes
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Inclusion Phenomena and Macrocyclic Chemistry"
DOI: 10.1007/s10847-020-00986-z
Abstract: Pillar[n]arenes have become a research hotspot in recent years. Because of its unique electron-rich cavity and easy functionalization, pillar[n]arenes have been extensively studied as carrier materials for applications in materials science, life science, nanoscience, information… read more here.
Keywords: diversified application; pillar arenes; application pillar; advances diversified ... See more keywords
Making pillar[6]arenes to lean: an art of tuning a supramolecular host
Sign Up to like & getrecommendations! Published in 2018 at "Science China Chemistry"
DOI: 10.1007/s11426-018-9362-0
Abstract: Symmetry and pattern are valuable forms of beauty that can be cherished on both the macroscopic and molecular levels. Scientists have always appreciated the intimate connections between symmetry and molecular structures, which is reflected in… read more here.
Keywords: pillar arenes; chemistry; phenylene rings; symmetry ... See more keywords
Rim-differentiated pillar[5]arenes
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2021.04.046
Abstract: ABSTRACT Pillar[5]arenes, designed and prepared by Ogoshi et al. in 2008 initially, refer to fifth classical macrocyclics. Among a wide range of pillar[5]arenes, rim-differentiated pillar[5]arenes containing five identical substituents on one rim and five different… read more here.
Keywords: differentiated pillar; arenes rim; rim differentiated; pillar arenes ... See more keywords
Radiation stability of alkylated pillar[5]arenes
Sign Up to like & getrecommendations! Published in 2019 at "Radiation Physics and Chemistry"
DOI: 10.1016/j.radphyschem.2019.03.025
Abstract: Abstract Radiation stability of methoxypillar[5]arene (1) and n-butoxypillar[5]arene (2) was studied by an electron accelerator with dose up to 14 MGy in air at room temperature. The radiolysis products and the possible radiolytic mechanism were also… read more here.
Keywords: radiation; stability alkylated; alkylated pillar; pillar arenes ... See more keywords
Critical Role of Achiral Guest Molecules in Planar Chirality Inversion of Alanine-Appended Pillar[5]arenes.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b00277
Abstract: Planar chirality inversion of pillar[5]arenes bearing d- or l-alanine substituents on both rims was investigated upon addition of guest molecules having pyridinium or imidazole moieties and long alkyl chains. The d- and l-alanine-substituted pillar[5]arenes exhibited… read more here.
Keywords: guest molecules; chirality; pillar arenes; planar chirality ... See more keywords
Pre-regulation of the planar chirality of pillar[5]arenes for preparing discrete chiral nanotubes†
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Science"
DOI: 10.1039/d1sc00074h
Abstract: Regulating the chirality of macrocyclic host molecules and supramolecular assemblies is crucial because chirality often plays a role in governing the properties of these systems. Herein, we describe pillar[5]arene-based chiral nanotube formation via pre-regulation of… read more here.
Keywords: chirality; pillar arenes; pre regulation; planar chirality ... See more keywords
Neutral isocyanide-templated assembly of pillar[5]arene [2] and [3]pseudorotaxanes.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02255a
Abstract: Unprecedented pillar[5]arene-isocyanide pseudorotaxane complexes are reported. Extensive 1H-NMR experiments reveal remarkably strong binding affinities of alkyl diisocyanide guests (Ka > 105 M-1 in CDCl3) by pillar[5]arenes. Characterised by multinuclear 1H and 13C-NMR spectroscopy and single-crystal… read more here.
Keywords: pillar arenes; isocyanide templated; pillar arene; arene ... See more keywords
Noncovalently bound and mechanically interlocked systems using pillar[n]arenes.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Society reviews"
DOI: 10.1039/d2cs00169a
Abstract: Pillar[n]arenes are pillar-shaped macrocyclic compounds owing to the methylene bridges linking the para-positions of the units. Owing to their unique pillar-shaped structures, these compounds exhibit various excellent properties compared with other cyclic host molecules, such… read more here.
Keywords: pillar shaped; pillar arenes; noncovalently bound; pillar arene ... See more keywords
Autonomous macroscopic signal deciphering the geometric self-sorting of pillar[n]arenes.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01372c
Abstract: In this communication, we have deciphered the geometric self-sorting of pillar[n]arenes by analyzing the fluid flow pattern obtained during the self-assembly of complementary pillar[n]arenes on the surface. The concept was further extended to demonstrate flow… read more here.
Keywords: pillar arenes; geometric self; sorting pillar; autonomous macroscopic ... See more keywords
The Role of Calix[n]arenes and Pillar[n]arenes in the Design of Silver Nanoparticles: Self-Assembly and Application
Sign Up to like & getrecommendations! Published in 2020 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms21041425
Abstract: Silver nanoparticles (AgNPs) are an attractive alternative to plasmonic gold nanoparticles. The relative cheapness and redox stability determine the growing interest of researchers in obtaining selective plasmonic and electrochemical (bio)sensors based on silver nanoparticles. The… read more here.
Keywords: arenes pillar; silver nanoparticles; calix arenes; self assembly ... See more keywords
Surfactant Effect on the Physicochemical Characteristics of Solid Lipid Nanoparticles Based on Pillar[5]arenes
Sign Up to like & getrecommendations! Published in 2022 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms23020779
Abstract: Novel monosubstituted pillar[5]arenes containing both amide and carboxyl functional groups were synthesized. Solid lipid nanoparticles based on the synthesized macrocycles were obtained. Formation of spherical particles with an average hydrodynamic diameter of 250 nm was… read more here.
Keywords: lipid nanoparticles; arenes surfactant; solid lipid; nanoparticles based ... See more keywords