Catalytic Enantioselective Pinacol and Meinwald Rearrangements for the Construction of Quaternary Stereo-centers.
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DOI: 10.1021/jacs.9b04551
Abstract: The development of enantioselective pinacol rearrangement is ex-tremely challenging due to the likelihood involvement of the carbeni-um intermediate that renders the stereochemical communication between catalyst and substrate difficult to achieve. Herein, we report chiral N-triflyl… read more here.
Keywords: catalytic enantioselective; rearrangements construction; meinwald rearrangements; pinacol meinwald ... See more keywords